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4-Chloro-2-nitroaniline | CAS 89-63-4

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4-Chloro-2-nitroaniline Basic information

Product Name:4-Chloro-2-nitroaniline
Synonyms:fastred2ncsalt;redbase3gl;redbasecibavi;redbaseirgavi;redsaltcibavi;redsaltnbgl;Sanyo Fast Red Salt 3GL;sanyofastredsalt3gl
CAS:89-63-4
MF:C6H5ClN2O2
MW:172.57
EINECS:201-925-4
Product Categories:Dyestuff Intermediates;Amines;Aromatics;Mutagenesis Research Chemicals;Anilines, Aromatic Amines and Nitro Compounds;Organics;Intermediates of Dyes and Pigments
Mol File:89-63-4.mol

4-Chloro-2-nitroaniline Chemical Properties

Melting point 117-119 °C(lit.)
Boiling point 200°C (rough estimate)
density 1.37
refractive index 1.6460 (estimate)
Fp 191 °C
storage temp. room temp
solubility 0.5g/l (anhydrous substance)
pkapK1: 1.10(+1) (25°C)
Colour Index 37040
form Crystalline Powder or Chunks
color Orange
PH7 (0.5g/l, H2O, 20℃)
Water Solubility INSOLUBLE
BRN 512436
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference89-63-4(CAS DataBase Reference)
NIST Chemistry ReferenceAniline, 4-chloro-2-nitro-(89-63-4)
EPA Substance Registry System4-Chloro-2-nitroaniline (89-63-4)

Safety Information

Hazard Codes T+,N,T
Risk Statements 26/27/28-33-51/53
Safety Statements 28-36/37-45-61-28A
RIDADR UN 2237 6.1/PG 3
WGK Germany 2
RTECS BX1575000
Autoignition Temperature964 °F
Hazard Note Very Toxic
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29214210
Hazardous Substances Data89-63-4(Hazardous Substances Data)

MSDS Information

ProviderLanguage
4-Chloro-2-nitroaniline English
SigmaAldrich English
ACROS English
ALFA English

4-Chloro-2-nitroaniline Usage And Synthesis

UsesUsesPreparationAir & Water ReactionsHazardPurification Methods
Chemical Propertiesbright orange powder
A nitro-aromatic amine with mutagenicity and carcinogenicity
Uses4-Chloro-2-nitroaniline is usedalmost exclusively as an intermediate in the synthesis ofpigments.The greatest potential for human exposure to 4-chloro-2-nitroaniline is in production and use of pigments made fromthe compound.
4-Chloro-2-nitroaniline is used as pharmaceutical intermediate.
Production Methods1,4-Dichloro-2-nitrobenzene is aminated at 165 ℃ by using a process similar to that described for 2- nitroaniline.
4-Chloro-2-nitrobenzenamine of chlorine.
General DescriptionBright orange powder.
Insoluble in water.
Reactivity Profile4-Chloro-2-nitroaniline forms explosive products on reaction with nitric acid. Can react with oxidizing agents.
Toxic by ingestion and inhalation.
Fire Hazard4-Chloro-2-nitroaniline is probably combustible.
Crystallise the aniline from hot H2O (m 115.8-116o), EtOH, EtOH/H2O or *C6H6, and dry it for 10hours at 60o in vacuo. It has m 115.5-116o after sublimation. [Beilstein 12 H 729, 12 I 355, 12 II 396, 12 III 1649, 12 IV 1669.]

4-Chloro-2-nitroaniline Preparation Products And Raw materials

Raw materials2,5-Dichloronitrobenzene-->4-Chloro-2-nitroaniline
Preparation ProductsQuizalofop-p-ethyl-->HANSA YELLOW 10G-->2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole-->N-Acetyl-N-(4-chloro-2-nitrophenyl)acetamide-->5-[(4-chloro-2-nitrophenyl)azo]-1-ethyl-1,2-dihydro-6-hydroxy-4-methyl-2-oxonicotinonitrile-->1,2,3,4-tetrahydro-Phenazine-->N-(2-AMINO-4-CHLOROPHENYL)ANTHRANILIC ACID-->8-chloro-1-phenyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione-->4-AMINO-3-NITROPHENYLBORONIC ACID, PINACOL ESTER-->5-CHLORO-2-IODOANILINE-->UV-320-->2,3,6-TRICHLOROQUINOXALINE-->DISPERSE YELLOW 211-->4-Chloro-2-nitroaniline

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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